Wednesday, 23 November 2016

Bubble Bubble and maybe not Toil and Trouble.

As atmospheric carbon dioxide (CO2) levels rise, very few coastal marine ecosystems will be spared the impacts of ocean acidification. Localized natural and human influences result in large diel variations in the oceans carbon chemistry which have negative impacts across a range of marine taxa: with the greatest impact on respiration, motility, and fertility.
With the increasing knowledge of anthropogenic stressors in coastal ecosystem many studies have tried to establish mitigation strategies. However these approaches have been limited in scope and results have been disappointing. Currently CO2 bubble stripping technology can be found in aquacultures, however the concept has been largely ignored for natural coastal environments.
Koweek and his team (2016) set out to evaluate a new geochemical engineering approach to reduce aqueous pH, pCO2, and Ω, through pumping air into the water as bubble plumes, as COwill natural diffuse into the air bubbles if the COConcentration is lower, effectively removing the COfrom the water.

Three models were developed before experimentation, the first model predicted that the amount of air-sea CO2 flux would be far greater when bubble stripping was implemented in a biologically active shallow coastal ecosystem. The second model found that high levels of water advection reduced the ability of the bubble stripping, however this could be overcome by increasing gas flow rates. The final model predicted that bubble stripping technology would work more efficiently in predicated marine conditions for the end of the century.

Experiments were then carried out replicating the models in closed tanks, the results closely matched the predictions from the computer models, giving the team confidence in their accuracy. The bubble stripping technology increases the transfer rate of CO2 between the ocean and the air up to 30 times faster than natural processes. The results from the model and experiment show that the installation of bubble stripping may prove useful for protecting small sections of shallow coastline that are ecologically or commercially important. 

Experimentally there were very few problems, however conceptually there are some major hurdles surrounding the implementation of bubble stripping. Would it be possible to comprehensively evaluate the ecological responses of the bubbling system in the natural environment? How would the equipment survive the variable conditions found in these environments? And where would the team obtain funding for large scale implementation? It should also be noted that the COthat bubble stripping removes from the seawater will increase the concentration in the air. That will in turn increase the rate of diffusion/solution back into the water so bubble stripping technology is only a temporary local solution unless combined with carbon capture technology which sequesters carbon in solid form or as liquefied CO2.

There haven’t been any significant publications in the same area released since this publication, however the obvious next step would be to conduct in-situ experiments which will be highly anticipated. Koweet and his team also made a passing comment mentioning that this technique may be applicable not only for coral habitats but for many other shallow coastal environments such as salt marshes and mangroves, opening up more areas of potential research.

The future of bubble stripping as a re-mediation technique is uncertain at this point as there are many factors that may derail this emerging technology. However this study has established an important foundation for bubble stripping technology and if this technique is as beneficial as promised, this could be a pivotal moment in shallow coastal water conservation and management.

Paper Reviewed 

Koweek, D., Mucciarone, D. and Dunbar, R. (2016). Bubble Stripping as a Tool To Reduce High Dissolved CO 2 in Coastal Marine Ecosystems. Environmental Science & Technology, 50(7), pp.3790-3797.

3 comments:

  1. Hello Stefan,

    thanks for your post! I have never heard of the idea of removing CO2 from the water before. You mention that this mechanism is only a " temporary local solution". I feel that the whole project will not work. The problem I see is that obviously the CO2 would be removed of the water and would therefore be enriched in the air. That would directly result in a reabsorbtion of CO2 by the water, if I got it right. Furthermore I don't think that you can remove the CO2 locally. What would you do with the gas once removed from the water? Storing somewhere? How preventing the gas to be immediately reabsorbed by the water?
    Maybe I'm missing important points because I have not read the paper.
    How do you feel about these points? Do you think that further research could solve these problems or is it really unrealistic to remove CO2 from the water as I think right now?
    I would be happy to hear your opinion on this!

    Thanks,
    Eleni

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    Replies
    1. Hi Eleni,

      You pointed out the major flaws with this technique! I mention these flaws towards the end of fourth paragraph and without sequestration technology it would just be reabsorbed.

      However after reading this paper, I think it focuses on the short term solution of protecting the reefs from the current conditions rather than removing carbon permanently.

      Currently from my understanding of carbon capture and storage it is developing, but the the costs associated with such a reduction of CO2 emissions are large and not enforced. The main routes of storage at the moment are Cement production and Geological storage, where we inject CO2 into geological formations.

      Currently at our stage of CC&S development, the storage of CO2 is possible, yet expensive and inadequate. Time and future investments will hopefully make this technology more common place and hopefully one day reduce the atmospheric CO2 levels back to pre-industrial times.

      Sorry if this seems a bit cluttered, If you would like me to go into anything in a bit more depth, feel free to ask :)

      Stefan

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  2. Hi Stefan,

    An interesting idea but I am sceptical of it's real world potential. I agree with you and Eleni that without some way of sequestering the CO2 from the air, this method just becomes a conveyor belt for carbon, moving it around rather than fixing it.
    As well as this, unless on an absolutely enormous scale, I fail to see how it would have any significant effect on reducing the amount of dissolved CO2 in the ocean, even if only designed to aid coastal regions.

    How do you think this technology could affect microbial populations, if at all?
    It may be a possibility that all of the bubbles bursting increases aerosolization of particles such as viruses, which could possibly alter the host-virus dynamics of many different species. Some algae blooms are often terminated by host-specific viruses, so maybe increased aerosolization could alter the duration or size of blooms, which may in turn have ramifications for nutrient cycles.

    Of course this is extremely speculative, but interesting non the less to think about how technology to solve our global issues, might actually cause some of its own.

    Thanks,
    Tabby

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